Search results for "Electron paramagnetic resonance spectroscopy"
showing 10 items of 12 documents
Structural analysis of Cu(II) ligation to the 5'-GMP nucleotide by pulse EPR spectroscopy.
2007
JBIC Journal of Biological Inorganic Chemistry, 12 (6)
Dialkyl(butadiene)cyclopentadienylmolybdenum(III) Complexes. Synthesis, Characterization, and Reactivity
2000
International audience; Treatment of CpMo(η4-diene)Cl2 (diene = 1,3-butadiene, C4H6, 1‘; isoprene, C5H8, 1‘ ‘; 2,3-dimethyl-1,3-butadiene, C6H10, 1‘ ‘) in diethyl ether at low temperature with 2 equiv of alkylmagnesium RMgX reagents affords the corresponding dialkyl complexes CpMo(η4-1,3-diene)R2 (2, 2‘, 2‘ ‘, R = CH3, a; CH2Ph, b; CH2SiMe3, c). These species are isolable in moderate yields and have been fully characterized by EPR, elemental analyses, and cyclic voltammetry. They all show a reversible reduction process at relatively low potentials and an irreversible oxidation. The structure of 2‘ ‘a was confirmed by single-crystal X-ray diffraction. The mixed complex CpMo(η4-C4H6)Cl(CH3), …
Radiācijas defektu EPR fluorīdu kristālos un oksifluorīdu stikla keramikā
2008
Elektroniskā versija nesatur pielikumus
Measurement of white wines resistance against oxidation by Electron Paramagnetic Resonance spectroscopy
2018
International audience; Free radical theory of aging hypothesizes that oxygen-derived radicals are responsible for the storage-related flavor instability in wine. In an optimal situation, a balanced-distribution exists between oxidants and antioxidants among wines intrinsic/extrinsic metabolites. Based on the kinetic study of POBN-1-hydroxyethyl spin adduct (POBN-1-HER) formation in wines initiated via the Fenton reaction, a novel tool based on EPR spin trapping methodology was developed to quantify wines resistance against oxidation. Antioxidant capacities of wines were evaluated according to POBN-1-HER maximum signal intensity (Imax POBN-1-HER) and rate formation (r(POBN-1-HER)) kinetic p…
Temperature dependence of the isotropic hyperfine coupling constants in 1,4-hydroquinone and 1,4-dihydroxynaphthalene cation radicals
1998
Evaluation of the original dose in irradiated dried fruit by EPR spectroscopy
2011
Abstract The electron paramagnetic resonance spectroscopy (EPR) is one of the physical methods, recommended by the European Committee for Standardization, for the identification of irradiated food containing cellulose, such as dried fruit. In this work the applicability of EPR as identification method of irradiated pistachios, hazelnuts, peanuts, chestnuts, pumpkin seeds is evaluated; the time stability of the radiation induced signal is studied and the single aliquot additive dose method is used to evaluate the dose in the product.
Properties of HO2• radicals induced by γ-ray irradiation in silica nanoparticles
2014
Abstract We report an experimental investigation on the effects of γ -ray irradiation in several types of silica nanoparticles previously loaded with O 2 molecules. They differ in specific surface and average diameter. By electron paramagnetic resonance (EPR) measurements we observe the generation of about 10 18 HO 2 • /cm 3 interstitial radicals. These radicals are induced by reaction of interstitial O 2 molecules with radiolytic H atoms, as previously suggested for O 2 -loaded bulk a-SiO 2 samples. However, at variance with respect to bulk materials, our experimental evidences suggest a different generation process of HO 2 • radical. In fact, by a detailed study of samples exposed to D 2 …
Investigation on the ganaration process of HO2• radicals by γ-ray irradiation in O2-loaded fumed silica
2013
Abstract We report an experimental investigation on the effects of γ-ray irradiation in three types of fumed silica previously loaded with O 2 molecules. Our data indicate that the main effect of irradiation in these systems is to generate a very large concentration of HO 2 interstitial radicals (about 10 18 molecules/cm 3 ). Furthermore, the number of generated HO 2 was found to be larger in the samples with higher O 2 contents before irradiation. This correlation suggests that HO 2 radicals are induced by reaction of interstitial O 2 molecules with radiolytic H atoms, as previously suggested for O 2 -loaded bulk amorphous silicon dioxide (a-SiO 2 or silica) samples. However, at variance …
Radiācijas defektu pētījumi ar EPR metodi LiBaF3 kristālā
2004
Izpētīts ar rentgenu istabas temperatūrā apstarotā L i B a F 3 kristālā radīta defekta EPR spektrs. EPR spektrs sastāv no apmēram 35 ekvidistantām līnijām. Defekts ir nestabils Jienas gaismā, bet tumsā sabrūk dažu stundu laikā. Šīs līnijas magnētiskā lauka orientācijā mralēli [111] kristāla asij atrodas vienādos attālumos (ar soli 0,9 mT) ar intensitāšu sadalījumu tuvu binomiālajam. EPR spektru var aprakstīt kā nesapārota spina S = 1/2 hiper- >īkstruktūras (liss) mijiedarbību ar divām ekvivalentu kaimiņu kodolu spinu grupām: 2 Li kodoliem pirmajā grupā un 8 F kodoliem otrajā grupā. Šāds modelis atbilst F-tipa centram elektrons atrodas fluora vakancē) LiBaF3 kristālā. Līniju intensitāšu stip…